Fukazawa-publication

> Original Papers

53. Negative Fluorescence Anisotropy of Phosphole Oxide-Based Dyes in Nematic Liquid Crystals

Takuya Ohzono, Tetsuro Yatabe, Chenguang Wang, Aiko Fukazawa, Shigehiro Yamaguchi

Communications Chemistry, accepted.

52. End-Capping π-Conjugated Systems with Medium-Sized Sulfur-Containing Rings: A Route Towards Solution-Processable Air-Stable Semiconductors

Aiko Fukazawa, Yusuke Toda, Masahiro Hayakawa, Anna Sekioka, Hiroyuki Ishii, Toshihiro Okamoto, Jun Takeya, Yuh Hijikata, Shigehiro Yamaguchi

Chem. Eur. J., 13, 24, 11503-11510 (2018).

[DOI: 10.1002/chem.201802656]

51. Water-Soluble Phospholo[3,2-b]phosphole P,P’-Dioxide-Based Fluorescent Dyes with High Photostability

Chenguang Wang, Aiko Fukazawa, Yoshiyuki Tanabe, Naoto Inai, Daisuke Yokogawa, Shigehiro Yamaguchi

Chem. Eur. J., 13, 1616-1324 (2018).

[DOI: 10.1002/asia.201800533]

50. Near Infrared Two-Photon-Excited and -Emissive Dyes Based on a Strapped Excited-State Intramolecular Proton-Transfer (ESIPT) Scaffold

Naoya Suzuki, Kayo Suda, Daisuke Yokogawa, Hirotaka Kitoh-Nishioka, Stephan Irle, Akihiro Ando, Luis M. G. Abegão, Kenji Kamada, Aiko Fukazawa, Shigehiro Yamaguchi

Chem. Sci., 9, 2666-2673 (2018).

[DOI: 10.1039/C8SC00066B]

Highlighted as an Inside Back Cover

49. Uncovering Different States of Topological Defects in Schlieren Textures of a Nematic Liquid Crystal

Takuya Ohzono, Kaoru Katoh, Chenguang Wang, Aiko Fukazawa, Shigehiro Yamaguchi, Jun-ichi Fukuda

Sci. Rep., 7, 16814 (2017).

[DOI: 10.1038/s41598-017-16967-1]

48. Photochemical Intramolecular C–H Addition of Dimesityl(hetero)arylboranes by a [1,6]-Sigmatropic Rearrangement

Naoki Ando, Aiko Fukazawa, Tomokatsu Kushida, Yoshihito Shiota, Shuhei Itoyama, Kazunari Yoshizawa, Yasunori Matsui, Yutaro Kuramoto, Hiroshi Ikeda, Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 56, 12210-12214 (2017).

[DOI: 10.1002/anie.201706929]

47. Super-Photostable Phosphole-Based Dye for Multiple-Acquisition Stimulated Emission Depletion Imaging

Chenguang Wang, Masayasu Taki, Yoshikatsu Sato, Aiko Fukazawa, Tetsuya Higashiyama, Shigehiro Yamaguchi

J. Am. Chem. Soc., 139, 10374-10381 (2017).

[DOI: 10.1021/jacs.7b04418]

プレスリリース（名古屋大学）>> LINK

46. Synthesis of Seminaphtho-phospha-fluorescein Dyes Based on the Consecutive Arylation of Aryldichlorophosphines

Aiko Fukazawa, Junichi Usuba, Raúl A. Adler, Shigehiro Yamaguchi

Chem. Commun., 53, 8565-8568 (2017).

[DOI: 10.1039/C7CC04323F]

45. Structures and Physical Properties of Chemically Reduced Diindenosiloles and Their π-Extended Derivatives

Ryo Takano, Ryo Shintani, Aiko Fukazawa, Shigehiro Yamaguchi, Koji Nakabayashi, Shin-ichi Ohkoshi, Kyoko Nozaki

Organometallics, 36, 2646-2653 (2017).

[DOI: 10.1021/acs.organomet.7b00260]

44. A Near Infrared Dye that Undergoes Multiple Interconversions via Acid-Base Equilibria and Reversible Redox Processes

Kengo Asai, Aiko Fukazawa, Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 56, 6848-6852 (2017).

[DOI: 10.1002/anie.201702140]

43. Tuning the Photophysical Properties of Photostable Benzo[b]phosphole P-Oxide-Based Fluorophores

Raúl A. Adler, Chenguang Wang, Aiko Fukazawa, Shigehiro Yamaguchi

Inorg. Chem., 56, 8718-8725 (2017).

[DOI: 10.1021/acs.inorgchem.7b00658]

42. Synthesis and Physical Properties of Strained Doubly Phosphorus-Bridged Biaryls and Viologens

Tobias W. Greulich, Eriko Yamaguchi, Carsten Doerenkamp, Constantin G. Daniliuc, Aiko Fukazawa, Hellmut Eckert, Shigehiro Yamaguchi, Armido Studer

Chem. Eur. J., 23, 6029-6033 (2017).

[DOI: 10.1002/chem.201605272]

41. Facile Synthesis of Polycyclic Pentalenes with Enhanced Hückel Antiaromaticity

Hiroya Oshima, Aiko Fukazawa, Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 56, 3270-3274 (2017).

[DOI: 10.1002/anie.201611344]

Highlighted as a Back Cover (Issue 12, March 13, 2017)

Highlighted in SYNFACT

40. Stable Red-Emissive Cationic Dithienotropylium Dyes

Kengo Asai, Aiko Fukazawa, Shigehiro Yamaguchi

Chem. Eur. J., 22, 17571-17575 (2016).

[DOI: 10.1002/chem.201604509]

39. A Macrocyclic Fluorophore Dimer with Flexible Linkers: Bright Excimer Emission with Long Fluorescence Lifetime

Hiroshi Osaki, Chih-Ming Chou, Masayasu Taki, Kai Welke, Daisuke Yokogawa, Stephan Irle, Yoshikatsu Sato, Tetsuya Higashiyama, Shohei Saito, Aiko Fukazawa, Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 55, 7131-7315 (2016).

[DOI: 10.1002/anie.201602239]

Highlighted as a Hot Paper

38. A Biphenyl Containing Two Electron-Donating and Two Electron-Accepting Moieties: A Rigid and Small Donor–Acceptor–Donor Ladder System

Tobias W. Greulich, Naoya Suzuki, Constantin G. Daniliuc, Aiko Fukazawa, Eriko Yamaguchi, Armido Studer, Shiehiro Yamaguchi

Chem. Commun., 52, 2374-2377 (2016).

[DOI: 10.1039/C5CC03063C]

37. Phospha-fluorescein: A Red-Emissive Fluorescein Analogue with High Photobleaching Resistance

Aiko Fukazawa, Shinji Suda, Masayasu Taki, Eriko Yamaguchi, Marek Grzybowski, Yoshikatsu Sato, Tetsuya Higashiyama, Shigehiro Yamaguchi

Chem. Commun., 52, 1120-1123 (2016).

[DOI: 10.1039/C5CC09345G]

Highlighted as a Cover Picture in Issue 6, 2016

36. A Phosphole Oxide Based Fluorescent Dye with Exceptional Resistance to Photobleaching: A Practical Tool for Continuous Imaging in STED Microscopy

Chenguang Wang, Aiko Fukazawa, Masayasu Taki, Yoshikatsu Sato, Tetsuya Higashiyama, Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 54, 15213-15217 (2015).

[DOI: 10.1002/anie.201507939]

プレスリリース (名古屋大学) >> LINK

研究ハイライト（ITbM）>> LINK

35. A Benzophosphole P-Oxide with an Electron-Donating Group at 3-Position: Enhanced Fluorescence in Polar Solvents

Eriko Yamaguchi, Aiko Fukazawa, Youhei Kosaka, Daisuke Yokogawa, Stephan Irle, Shigehiro Yamaguchi

Bull. Chem. Soc. Jpn., 88, 1545-1552 (2015).

[DOI: 10.1246/bcsj.20150238]

Highlighted as a Selected Paper in Issue 11, 2015

34. A Red-emitting Ratiometric Fluorescent Probe Based on a Benzophosphole P-Oxide Scaffold for the Detection of Intracellular Sodium Ions

Masayasu Taki, Hiroaki Ogasawara, Hiroshi Osaki, Aiko Fukazawa, Yoshikatsu Sato, Kimi Ogasawara, Tetsuya Higashiyama, Shigehiro Yamaguchi

Chem. Commun., 51, 11880-11883 (2015).

[DOI: 10.1039/C5CC03547C]

33. A Nonaromatic Thiophene-Fused Heptalene and Its Aromatic Dianion

Hiroya Oshima, Aiko Fukazawa, Takahiro Sasamori, Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 54, 7636-7639 (2015).

[DOI: 10.1002/anie.201501790]

32. A Cyclic Octithiophene Containing β,β’-Linkages

Kengo Asai, Aiko Fukazawa, S. Yamaguchi

Chem. Commun., 51, 6096-6099 (2015).

[DOI: 10.1039/C5CC00570A]

31. Environment-Sensitive Fluorescent Probe: A Benzophosphole Oxide with an Electron-Donating Substituent

Eriko Yamaguchi, Chenguang Wang, Aiko Fukazawa, Masayasu Taki, Yoshikatsu Sato, Taeko Sasaki, Minako Ueda, Narie Sasaki, Tetsuya Higashiyama, Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 54, 4539-4543 (2015).

[DOI: 10.1002/anie.201500229]

Selected as an Inside Cover in Issue 15, 7 April 2015

30. A Strap Strategy for Construction of an Excited-State Intramolecular Proton Transfer (ESIPT) System with Dual Fluorescence

Naoya Suzuki, Aiko Fukazawa, Kazuhiko Nagura, Shohei Saito, Hirotaka Kitoh-Nishioka, Daisuke Yokogawa, Stephan Irle, Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 53, 8231-8235 (2014).

[DOI: 10.1002/anie.201404867]

29. Dearomatization-Induced Transannular Cyliczation: Synthesis of Electron-Accepting Thiophene-S,S-Dioxide-Fused Biphenylene

Aiko Fukazawa, Hiroya Oshima, Soji Shimizu, Nagao Kobayashi, and Shigehiro Yamaguchi

J. Am. Chem. Soc., 136, 8738-8745 (2014).

[DOI: 10.1021/ja503499n]

Highlighted in SYNFACTS

28. The B(C6F5)3 Boron Lewis Acid Route to Arene-Annulated Pentalenes

Chao Chen, Marcel Harhausen, Aiko Fukazawa, Shigehiro Yamaguchi, Roland Fröhlich, Constantin G. Daniliuc, Jeffrey L. Petersen, Gerald Kehr, Gergard Erker

Chem. Asian J., 9, 1671-1681 (2014).

[DOI: 10.1002/asia.201400096]

27. Synthesis of Pyridine N-Oxide-BF2CF3 Complexes and Their Fluorescence Properties

Tomoaki Nishida, Aiko Fukazawa, Eriko Yamaguchi, Hiroya Oshima, Shigehiro Yamaguchi, Motomu Kanai, Yoichiro Kuninobu

Chem. Asian J., 9, 1026-1030 (2014).

[DOI: 10.1002/asia.201301688]

26. Hydroxyphenyl-Substituted Benzophosphole Oxides: Impact of the Intramolecular Hydrogen Bond on the Fluorescence Properties

Aiko Fukazawa, Hiroshi Osaki, and Shigehiro Yamaguchi

Asian J. Org. Chem., 3, 122-127 (2014). (Special Issue: Pi-Conjugated Compounds for Organic Electronics)

[DOI: 10.1002/ajoc.201300227]

Highlighted as a Cover Picture in Issue 2, Feb 2014

25. Diarylated Bi(thieno[2,3-c]thiophene)s: A Ring-fusing Strategy for Controlling the Molecular Alignment of Oligoarenes

Aiko Fukazawa, Daisuke Kishi, Yuki Tanaka, Shu Seki, and Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 52, 12091-12095 (2013).

[DOI: 10.1002/anie.201306323]

24. Photochemical Double 5-exo-dig Cyclization of Alkenyl-substituted Dithienylacetylenes: Efficient Synthesis of Diarylated Dithienofulvalenes

Aiko Fukazawa, Takashi Karasawa, Hongyu Zhang, Kazumitsu Minemura, Christopher Camacho, Jian Wang, Stephan Irle, and Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 52, 10519-10523 (2013).

[DOI: 10.1002/anie.201303738]

23. Dibenzopentalenes by B(C6F5)3 Induced Cyclization Reactions of 1,2-Bis(phenylethynyl)benzenes

Chao Chen, Marcel Harhausen, René Liedtke, Kathrin Bussmann, Aiko Fukazawa, Shigehiro Yamaguchi, Jeffrey L. Petersen, Constantin G. Daniliuc, Roland Fröhlich, Gerald Kehr, and Gerhard Erker

Angew. Chem. Int. Ed., 52, 5992-5996 (2013).

[DOI: 10.1002/anie.201300871]

Highlighted in SYNFACTS

22. S-Pechmann Dye: A Thiolactone-Containing Organic Dye with Pronounced Electron-Accepting Character and Its Solid-State Photophysical Properties

Aiko Fukazawa, Makoto Adachi, Ken Nakakura, Shohei Saito, and Shigehiro Yamaguchi

Chem. Commun., 49, 7117-7119 (2013).

[DOI: 10.1039/C3CC41007B]

Highlighted in Back Cover in Issue 64, Aug 18 2013

21. Thiophene-Fused Bisdehydro[12]annulene That Undergoes Transannular Alkyne Cycloaddition by Either Light or Heat

Aiko Fukazawa, Hiroya Oshima, Yoshihito Shiota, Shouya Takahashi, Kazunari Yoshizawa, and Shigehiro Yamaguchi

J. Am. Chem. Soc., 135, 1731-1734 (2013).

[DOI: 10.1021/ja3126849]

Highlighted in SYNFACTS

20. Sequential Electrophilic and Photochemical Cyclizations from Bis(bithienyl)acetylene to a Tetrathienonaphthalene Core

Chuandong Dou, Shohei Saito, Libin Gao, Naoki Matsumoto, Takashi Karasawa, Hongyu Zhang, Aiko Fukazawa, and Shigehiro Yamaguchi

Org. Lett., 15, 80-83 (2013).

[DOI: 10.1021/ol303107y]

19. Reaction of Pentaarylboroles with Carbon Monoxide: An Isolable Organoboron Carbonyl Complex

Aiko Fukazawa, Jason L. Dutton, Cheng Fan, Lauren G. Mercier, Adrian Y. Houghton, Qiao Wu, Warren E. Piers, and Masood Parvez

Chem. Sci., 3, 1814-1818 (2012).

[DOI: 10.1039/C2SC20336G]

18. Electron-Donating Tetrathienyl-Substituted Borole

Takafumi Araki, Aiko Fukazawa, and Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 51, 5484-5487 (2012).

[DOI: 10.1002/anie.201201156]

17. Combined Experimental and Theoretical Studies on the Photophysical Properties of Cycloparaphenylenes

Yasutomo Segawa, Aiko Fukazawa, Sanae Matsuura, Haruka Omachi, Shigehiro Yamaguchi, Stephan Irle, and Kenichiro Itami

Org. Biomol. Chem., 10, 5979-5984 (2012).

[DOI: 10.1039/C2OB25199J]

16. Synthesis and Photophysical Properties of Aryl Substituted 2-Borylbenzaldimines and their Extended p-Conjugated Congeners

Benedikt Neue, Roland Fröhlich, Birgit Wibbeling, Aiko Fukazawa, Atsushi Wakamiya, Shigehiro Yamaguchi, and Ernst-Ulrich Würthwein

J. Org. Chem., 77, 2176-2184 (2012).

[DOI: 10.1021/jo202212s]

15. Bis(phosphoryl)-bridged Biphenyls by Radical Phosphanylaion: Synthesis, Photophysical and Electrochemical Properties

Achim Bruch, Aiko Fukazawa, Eriko Yamaguchi, Shigehiro Yamaguchi, and Armido Studer

Angew. Chem. Int. Ed., 50, 12094-12098 (2011).

[DOI: 10.1002/anie.201104114]

14. Synthesis and Structures of a Series of Bulky “Rind-Br” Based on a Rigid Fused-Ring s-Hydrindacene Skeleton

Tsukasa Matsuo, Katsunori Suzuki, Tomohide Fukawa, Baolin Li, Mikinao Ito, Yoshiaki Shoji, Takashi Otani, Liangchun Li, Megumi Kobayashi, Makoto Hachiya, the late Yoshiyuki Tahara, Daisuke Hashizume, Takeo Fukunaga, Aiko Fukazawa, Yongming Li, Hayato Tsuji, and Kohei Tamao

Bull. Chem. Soc. Jpn., 84, 1178-1191 (2011).

[DOI: 10.1246/bcsj.20110090] Open Access Article

Selected as the BCSJ Award Article in Nov. 2011 & Cover Picture

13. Zwitterionic Ladder Stilbenes with Phosphonium and Borate-Bridges: Intramolecular Cascade Cyclization and Structure-Photophysical Properties Relationship

Aiko Fukazawa, Eriko Yamaguchi, Emi Ito, Hiroshi Yamada, Jian Wang, Stephan Irle, and Shigehiro Yamaguchi

Organometallics, 30, 3870-3879 (2011).

[DOI: 10.1021/om200453w]

12. Phosphine Sulfides as an Anchor Unit for Single Molecule Junction

Aiko Fukazawa, Manabu Kiguchi, Satoshi Tange, Yasunori Ichihashi, Qiang Zhao, Takuya Takahashi, Tatsuya Konishi, Kei Murakoshi, Yuta Tsuji, Aleksandar Staykov, Kazunari Yoshizawa, and Shigehiro Yamaguchi

Chem. Lett., 40, 174-176 (2011).

[DOI: 10.1246/cl.2011.174]

Selected as Editor’s Choice

11. Intense Fluorescence of 1-Aryl-2,3,4,5-tetraphenylphosphole Oxides in the Crystalline State

Aiko Fukazawa, Yasunori Ichihashi, and Shigehoro Yamaguchi

New J. Chem., 34, 1537-1540 (2010). (Themed Issue: Main Group Chemistry)

[DOI: 10.1039/c0nj00155d]

Highlighted as an Inside Front Cover ([DOI: 10.1039/C0NJ90018D])

10. Thiophene-Fused Phospholo[3,2-b]phospholes and Their Dichalcogenides: Synthesis and Structure-Photophysical Properties Relationships

Aiko Fukazawa, Taka-aki Murai, Liangchun Li, Youming Chen, and Shigehiro Yamaguchi

C. R. Chimie, 13, 1082-1090 (2010) (Special issue: Phosphorus Chemistry Today).

[DOI: 10.1016/j.crci.2010.04.021]

9. Zwitterionic Ladder Bis(arylethenyl)benzenes with Large Two-Photon Absorption Cross Sections

Aiko Fukazawa, Hiroshi Yamada, Yutaka Sasaki, Seiji Akiyama, and Shigehiro Yamaguchi

Chem. Asian J., 5, 466-469 (2010).

[DOI: 10.1002/asia.200900517]

Most accessed articles in 01/2010

8. Benzo[b]phosphole-Containing π-Electron Systems: Synthesis Based on an Intramolecular trans-Halophosphanylation and Some Insights into Their Properties

Aiko Fukazawa, Yasunori Ichihashi, Youhei Kosaka, and Shigehiro Yamaguchi

Chem. Asian J., 4, 1729-1740 (2009).

[DOI: 10.1002/asia.200900303]

Most accessed articles in 10/2009

7. Structural Modification of Silicon-Bridged Ladder Stilbene Oligomers and Distyrylbenzenes

Hiroshi Yamada, Caihong Xu, Aiko Fukazawa, Atsushi Wakamiya, and Shigehiro Yamaguchi

Macro. Chem. Phys., 210, 904-916 (2009).

[DOI: 10.1002/macp.200900037]

6. Phosphonium and Borate-Bridged Zwitterionic Ladder Stilbene and Its Extended Analogues

Aiko Fukazawa, Hiroshi Yamada, and Shigehiro Yamaguchi

Angew. Chem. Int. Ed., 47, 5582-5585 (2008).

[DOI: 10.1002/anie.200801834]

Highlighted in SYNFACTS

5. Bis-Phosphoryl-Bridged Stilbenes Synthesized by an Intramolecular Cascade Cyclization

Aiko Fukazawa, Masanao Hara, Toshihiro Okamoto. Eun-Cheol Son, Caihong Xu, Kohei Tamao, and Shigehiro Yamaguchi

Org. Lett., 10, 913-916 (2008).

[DOI: 10.1021/ol7030608]

4. Coplanar Oligo(p-phenylenedisilenylene)s Based on the Octaethyl-Substituted s-Hydrindacenyl Groups

Aiko Fukazawa, Yongming Li, Shigehiro Yamaguchi, Hayato Tsuji, and Kohei Tamao

J. Am. Chem. Soc., 129, 14164-14165 (2007).

[DOI: 10.1021/ja0764207]

3. Skeletal Rearrangement of a Bicyclic 1,3-Diphenyltrisilane during Acid-Induced Dephenylation Reactions

Aiko Fukazawa, Hayato Tsuji, and Kohei Tamao

Silicon Chemistry, 3, 157-163 (2007).

[DOI: 10.1007/s11201-006-9022-7]

2. all-anti-Octasilane: Conformation Control of Silicon Chains Using the Robust Bicyclic Trisilane as the Building Block

Aiko Fukazawa, Hayato Tsuji, and Kohei Tamao

J. Am. Chem. Soc., 128, 6800-6801 (2006).

[DOI: 10.1021/ja0616231]

1. All-anti Pentasilane: Conformation Control of Oligosilanes Based on Bis(tetramethylene)-tethered Trisilane Unit

Hayato Tsuji, Aiko Fukazawa, Shigehiro Yamaguchi, Akio Toshimitsu, and Kohei Tamao

Organometallics 23, 3375-3377 (2004).

[DOI: 10.1021/om049695t]

> Accounts and Reviews

3. Phosphole P-Oxide-Containing π-Electron Materials: Synthesis and Applications in Fluorescence Imaging

Shigehiro Yamaguchi, Aiko Fukazawa, Masayasu Taki

J. Synth. Org. Chem., Jpn., 75, 1179-1187 (2017). [Open Access]

[DOI: 10.5059/yukigoseikyokaishi.75.1179]

2. Synthetic Study of Novel π-Electron Materials Containing Boron, Nitrogen, and Phosphorus as a Key Main Group Elements

Shigehiro Yamaguchi, Aiko Fukazawa

J. Syn. Org. Chem., Jpn., 69, 661-670 (2011).

1. Ladder pi-Conjugated Materials Containing Main Group Elements

Aiko Fukazawa, Shigehiro Yamaguchi

Chem. Asian J., 4, 1386-1400 (2009).

[DOI: 10.1002/asia.200900179]

(Most accessed articles in 07-08/2009, 2/2009-1/2010)

> 著書・解説記事 (in Japanese)

7. 超耐光性蛍光色素が拓く蛍光バイオイメージング

佐藤良勝，Chenguang Wang，深澤愛子，多喜正泰，東山哲也，山口茂弘

Plant Morphology, 28, 9913 (2016).

6. チオフェンの「適度な芳香族性」を鍵とするπ電子系のデザイン

深澤愛子

化学と工業, 66, 1000-1001 (2013).

5. 機能性材料への応用

深澤愛子，山口茂弘

現代ケイ素化学–基礎から応用まで，吉良満夫，玉尾皓平編，化学同人，pp. 333-347 (2013).

4. 芳香環を使った分子のだまし絵 – シクロビス[4]ヘリセンの合成

深澤愛子

化学, 67, 63-64 (2012).

3. 触媒の精密設計に基づく高速クロスカップリング反応の実現

深澤愛子

Organometallic News, 57 (2011).

2. ホスフィンオキシドで単分子層ができた！

深澤愛子

化学, 63, 67-68 (2008).

1. リンは窒素を超えられるか？ー機能性分子を指向した有機リン化学の最近の動向

深澤愛子，山口茂弘

化学, 61, 68-69 (2006).