Functional Organic Materials Laboratory 名古屋大学大学院理学研究科
物質理学専攻化学系 機能有機化学研究室


坂井 美佳 Mika Sakai


平成31年 GTR卓越大学院RA
令和2年 日本学術振興会特別研究員DC1


平成30年  日本化学会東海支部長賞
令和元年   ITbM-GTR Pre-ISNA Symposium Poster Award
令和元年  第46回有機典型元素化学討論会 優秀ポスター賞 (Chemistry Letters Young Award)

Publication List

Multiple Resonance Type Thermally Activated Delayed Fluorescence by Dibenzo[1,4]azaborine Derivatives
J. H. Bae, M. Sakai, Y. Tsuchiya, N. Ando, X.-K. Chen, T. B. Nguyen, C.-Y. Chan, Y.-T. Lee, M. Auffray, H. Nakanotani, S. Yamaguchi, C. Adachi
Front. Chem., in press (2022).

Planarized Phenyldithienylboranes: Effects of the Bridging Moieties and π-Extension on the Photophysical Properties and Lewis Acidity
M. Sakai, M. Mori, M. Hirai, N. Ando, S. Yamaguchi
Chem. Eur. J., e202200728 (2022).
[DOI: 10.1002/chem.202200728]

Electron-Deficient Heteroacenes that Contain Two Boron Atoms: Near-Infrared Fluorescence Based on a Push–Pull Effect
M. Ito, M. Sakai, N. Ando, S. Yamaguchi
Angew. Chem. Int. Ed., 60, 21853-21859 (2021).
[DOI: 10.1002/anie.202106642]

Regio- and Stereoselective 1,2-Carboboration of Ynamides with Aryldichloroboranes
C. You, M. Sakai, C. G. Daniliuc, K. Bergander, S. Yamaguchi, A. Studer
Angew. Chem. Int. Ed., 60, 21697-21701 (2021).
[DOI: 10.1002/anie.202107647]

Twofold C–H Activation Enables Synthesis of a Diazacoronene-type Fluorophore with Near Infrared Emission through Isosteric Replacement
S. Greßies, M. Ito, M. Sakai, H. Osaki, J. H. Kim, T. Gensch, C. Daniliuc, N. Ando, S. Yamaguchi, F. Glorius
Chem. Eur. J., 27, 2753-2759 (2021).
[DOI: 10.1002/chem.202004080]

Planarized B,N-Phenylated Dibenzoazaborine with a Carbazole Substructure: Electronic Impact of the Structural Constraint
M. Ando, M. Sakai, N. Ando, M. Hirai, S. Yamaguchi
Org. Biomol. Chem., 17, 5500-5504 (2019).
[DOI: 10.1039/c9ob00934e]

Structurally Constrained Boron-, Nitrogen-, Silicon-, and Phosphorus-Centered Polycyclic π-Conjugated Systems
M. Hirai, N. Tanaka, M. Sakai, S. Yamaguchi
Chem. Rev., 119, 8291-8331 (2019).
[DOI: 10.1021/acs.chemrev.8b00637]