Functional Organic Materials Laboratory Department of Chemistry, Graduate School of Science, Nagoya University
Institute of Transformative Bio-Molecules


Olefin–Borane Interactions in Donor–π–Acceptor Fluorophores that Undergo Frustrated-Lewis-Pair-Type Reactions
R. Oshimizu, N. Ando, S. Yamaguchi
Angew. Chem. Int. Ed., 61, e202209394 (2022).
  • DOI: 10.1002/anie.202209394
    A Negative-solvatochromic Fluorescent Probe for Visualizing Intracellular Distributions of Fatty Acid Metabolites
    K. Kajiwara, H. Osaki, S. Greßies, K. Kuwata, J-H. Kim, T. Gensch, Y. Sato, F. Glorius, S. Yamaguchi, M. Taki
    Nat. Commun., 13, 2533 (2022).
  • DOI: 10.1038/s41467-022-30153-6
  • 2022-4-11Publication
    Planarized Phenyldithienylboranes: Effects of the Bridging Moieties and π-Extension on the Photophysical Properties and Lewis Acidity
    M. Sakai, M. Mori, M. Hirai, N. Ando, S. Yamaguchi
    Chem. Eur. J., 28, e202200728 (2022).
  • DOI: 10.1002/chem.202200728
    Fluorescent Organic π-Radicals Stabilized with Boron: Featuring a SOMO–LUMO Electronic Transition
    M. Ito, S. Shirai, Y. Xie, T. Kushida, N. Ando, H. Soutome, K. J. Fujimoto, T. Yanai, K. Tabata, Y. Miyata, H. Kita, S. Yamaguchi
    Angew. Chem. Int. Ed., e202201965 (2022).
  • DOI: 10.1002/ange.202201965
    Fully Fused Boron-doped Polycyclic Aromatic Hydrocarbons: Their Synthesis, Structure–property Relationships, and Self-assembly Behavior in Aqueous Media
    H. Narita, H. Choi, M. Ito, N. Ando, S. Ogi, S. Yamaguchi
    Chem. Sci., 1484-1491 (2022).
  • DOI: 10.1039/D1SC06710A
  • 2021-11-27Publication
    Photobase-Driven Excited-State Intramolecular Proton Transfer (ESIPT) in a Strapped π-Electron System
    N. Suzuki, T. Kubota, N.i Ando, . Yamaguchi
    Chem. Eur. J., 27, e202103584 (2021).
  • DOI: 10.1002/chem.202103584
  • 2021-7-26Publication
    Regio- and Stereoselective 1,2-Carboboration of Ynamides with Aryldichloroboranes
    C. You, M. Sakai, C. G. Daniliuc, K. Bergander, S. Yamaguchi, A. Studer
    Angew. Chem. Int. Ed., 60, 21697-21701 (2021).
  • DOI: 10.1002/anie.202107647
  • 2021-6-11Publication
    Electron-Deficient Heteroacenes that Contain Two Boron Atoms: Near-Infrared Fluorescence Based on a Push–Pull Effect
    M. Ito, M. Sakai, N. Ando, S. Yamaguchi
    Angew. Chem. Int. Ed., in press (2021).
  • DOI: 10.1002/anie.202106642
  • 2021-5-29Publication
    Boron-Doped Polycyclic π-Electron Systems with an Antiaromatic Borole Substructure that Form Photoresponsive B–P Lewis Adducts
    N. Ando, T. Yamada, H. Narita, N. Oehlmann, M. Wagner, S. Yamaguchi
    J. Am. Chem. Soc., 143, 9944-9951 (2021).
  • DOI: 10.1021/jacs.1c04251
  • Selected as a Cover
    Late-stage Functionalisation of Alkyne-modified Phospha-Xanthene Dyes: Lysosomal Imaging Using an OFF-ON-OFF Type of pH Probe
    H. Ogasawara, Y. Tanaka, M. Taki, S. Yamaguchi
    Chem. Sci., 12, 7902-7907 (2021).
  • DOI: 10.1039/D1SC01705E
  • 2021-3-24Publication
    Donor–Acceptor–Acceptor-Type Near-infrared Fluorophores that Contain Dithienophosphole Oxide and Boryl Groups: Effect of the Boryl Group on the Nonradiative Decay
    Y. Sugihara, N. Inai, M. Taki, T. Baumgartner, R. Kawakami, T. Saitou, T. Imamura, T. Yanai, S. Yamaguchi
    Chem. Sci., 12, 6333-6341 (2021).
  • DOI: 10.1039/D1SC00827G
    Dual Trapping of a Metastable Planarized Triarylborane π-System Based on Folding and Lewis Acid–Base Complexation for Seeded Polymerization
    H. Choi, S. Ogi, N. Ando, S. Yamaguchi
    J. Am. Chem. Soc., 143, 2953-2961 (2021).
  • DOI: 10.1021/jacs.0c13353
    Fused Thiophene-S,S-dioxide-Based Super-Photostable Fluorescent Marker for Lipid Droplets
    M. Taki, K. Kajiwara, E. Yamaguchi, Y. Sato, S. Yamaguchi
    ACS Materials Lett., 3, 42-49 (2021).
  • DOI: 10.1021/acsmaterialslett.0c00451
    Twofold C–H Activation Enables Synthesis of a Diazacoronene-type Fluorophore with Near Infrared Emission through Isosteric Replacement
    S. Greßies, M. Ito, M. Sakai, H. Osaki, J. H. Kim, T. Gensch, C. Daniliuc, N. Ando, S. Yamaguchi, F. Glorius
    Chem. Eur. J., 27, 2753-2759 (2020).
  • DOI: 10.1002/chem.20204080
    Dithieno[a,e]pentalenes: Highly Antiaromatic Yet Stable π‐Electron Systems without Bulky Substituents
    J. Usuba, M. Hayakawa, S. Yamaguchi, A. Fukazawa
    Chem. Eur. J., 27, 1638-1647 (2021).
  • DOI: 10.1002/chem.20204244
  • 2020-09-16Publication
    Hydrophobicity-driven Folding and Seeded Polymerization of Cystine-based Dimeric Diamides in Aqueous Media
    N. Fukaya, S. Ogi, M. Kawashiro, S. Yamaguchi
    Chem. Commun., 56, 12901-12904 (2020).
  • DOI: 10.1039/D0CC05255H
  • Selected as a Front Cover
  • Selected as a Hot article
  • 2020-09-03Publication
    Long-lived charge transfer state from B-N frustrated Lewis pairs enchained in supramolecular copolymers
    B. Adelizzi, P. Chidchob, N. Tanaka, B. A.G. Lamers, S. C. J. Meskers, S. Ogi, A. R. A. Palmans, S. Yamaguchi, E. W. Meijer
    J. Am. Chem. Soc., 142, 16681-16689 (2020).
  • DOI: 10.1021/jacs.0c06921
  • 2020-07-01Publication
    A Near-Infrared Emissive p-Conjugated Polymer Consisting of an Excited-state Intramolecular Prorotn Transfer Unit
    N. Suzuki, M. Wakioka, F. Ozawa, S.Yamaguchi
    Asian J. Org. Chem., 9, 1326-1332 (2020).
  • DOI: 10.1002/ajoc.202000234
    Phosphole-oxide-based Fluorescent Probe for Super-resolution Stimulated Emission Depletion (STED) Live Imaging of the Lysosome Membrane
    C. Wang, M. Taki, K. Kajiwara, J. Wang, S.Yamaguchi
    ACS Materials Lett., 2, 705-711 (2020).
  • DOI: 10.1021/acsmaterialslett.0c00147
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    Furomachi, Chikusa-ku, Nagoya 464-8602
    Institute of Transformative Bio-Molecules, Nagoya University
    Department of Chemistry, Graduate School of Science, Nagoya University, ITbM Building 3F / SA Building 4F
    Prof. Dr. Shigehiro Yamaguchi